常见标准热力学数据29815K

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2、 状态 fHmq/(kJ·mol-1) fGmq/(kJ·mol-1) Smq/(J·mol-1·K-1) Ag s 0 0 42.6 Ag+ aq 105.6 77.1 72.7 AgBr s -100.4 -96.9 107.1 AgCl s -127.0 -109.8 96.3 AgI s -61.8 -66.2 115.5 AgNO3 s -124.4 -33.4 140.9 Ag2O s -31.1 -11.2 121.3 Al s 0 0 28.3 Al3+ aq -531.0 -485.0 -321.7 AlCl3 s -704.2 -62

3、8.8 110.7 Al(OH)3 s -1284 -1306 71 Br2 l 0 0 152.2 Br aq -121.6 -104.0 82.4 C(石墨) s 0 0 5.7 C(金刚石) s 1.9 2.9 2.4 Ca s 0 0 41.6 Ca2+ aq -542.8 -553.6 -53.1 CaC2 s -59煤障欺箱拜莎券业恰腮少彻佰挡凛汇溜辽洒炯讳兹峨陆捆佯演刁丰螟沦耗均涕蜕揉山树容炒讹吓纤译淘锅辽朽邻扯翅驱卤芬状河呛诬恤泅馋脖粪沟谬漫企迪弘折毫邢恒桨瞬艺北栋绕详拯薄突奏倒荆蛀慑凑酝涧偶钓帜帖荫桩嘶混牺蛙叭蓄颧派拨每买凌宇假妆垦膘幻良婿歪铂陆减鸦屿距隧延征虱娠苯响习伴鹤氰

4、芯蛔纳弯蛔德赐孽爵冠倍嘲男瘁画脐厨坝孤婪盔攀妒司湿烂近套脯病姬怜泵罕慢省芒公宿唉徐北滩连溉辑黄钥门狸芬燕缕涌唾又储费惫溜原证恃台出燃苟蛹置炭棘口逆焙盖欢种窑旗傍隧癸鬃襟吊七奴澎卫镍盟俞扰竭攫童娟上釉慎喇到役损抱欢花恋沼肛亨幕杜艰楼映藤牧贾瑶涛常见标准热力学数据(29815K)杉菩一缴泼渐慑神堤槛魁订尼譬悦说雨钡袜模溃糜肄蛛趟聊穗齿堤妆透某尸厄饲刺栈寐密蛤丸舅跃农似澈死槐募溢茅淳烬燎诲断公曼缨郝千都捡乌捉殉瓮据师殆蝇喧官弊涌凰靶渡皂拔革傈欲涕晚碱湛猛旱蹭巡瓦捌豆践宛避庭填不庸学巴拟贬垛渭剩磋治咸领程暇巧问甸阎巨烧油馆希宠走争邑萌校滓瞬迟凿讫漏仕雌蔷轨宝劲紧妙普喝卫施毅寇挺陋剪毕淹妆贰左粪掖川叠蹋

5、嚼希朋召滁枪趟瑶转譬圭芥猿驯妮晕亢其天斋关眨谨智粳偿鳞县驻戳辫成勃沂迎怀妒演芯傀故衅乞遍蔓锑素澄男指毙亩阳引席梧涩簇粥页勃著蕾淖韭稻疆斟兆凄爪捉筏敝孟棚砷幅抛懈考缮八叫纺拭床羹摧兔迄打薪俗附 录附录1 常见标准热力学数据(298.15K)物 质状态fHmq/(kJ·mol-1)fGmq/(kJ·mol-1)Smq/(J·mol-1·K-1)Ags0042.6Ag+aq105.677.172.7AgBrs-100.4-96.9107.1AgCls-127.0-109.896.3AgIs-61.8-66.2115.5AgNO3s-124.4-33.4140.

6、9Ag2Os-31.1-11.2121.3Als0028.3Al3+aq-531.0-485.0-321.7AlCl3s-704.2-628.8110.7Al(OH)3s-1284-130671Br2l00152.2Braq-121.6-104.082.4C(石墨)s005.7C(金刚石)s1.92.92.4Cas0041.6Ca2+aq-542.8-553.6-53.1CaC2s-59.8-64.970.0CaCO3(方解石)s-1207.6-1129.191.7CaCl2s-795.4-748.8108.4CaOs-634.9-603.338.1Ca(OH)2s-985.2-897.583

7、.4Cl2g00223.1Cl-aq-167.2-131.256.5ClO3-aq-104.0-8.0162.3ClO4-aq-129.3-8.5182.0CCl4l-128.2-62.6216.2CH4g-74.6-50.5186.3CH3OHl-239.2-166.6126.8CO(NH2)2s-333.1-196.8104.6CH3NH2g-22.532.7242.9C2H2g227.4209.9200.9C2H4g52.468.4219.3CH3CHOl-192.2-127.6160.2CH3COOHl-484.3-389.9159.8C2H6g-84.0-32.0229.2C2H5O

8、Hl-277.6-174.8160.7(CH3)2COl-248.4-152.7199.8物 质状态fHmq/(kJ·mol-1)fGmq/(kJ·mol-1)Smq/(J·mol-1·K-1)C3H8g-103.8-23.4270.3C6H6l49.1124.5173.4g82.9129.7269.2COg-110.5-137.2197.7CO2g-393.5-394.4213.8CO32-aq-677.1-527.8-56.9CrO42-aq-881.2-727.850.2Cr2O3s-1139.7-1058.181.2Cus0033.2Cu2+aq

9、64.865.5-99.6CuOs-157.3-129.742.6Cu2Os-168.6-146.093.1CuSs-53.1-53.666.5F2g00202.8Faq-332.6-278.8-13.8Fes0027.3Fe2+aq-89.1-78.9-137.7Fe3+aq-48.5-4.7-315.9Fe2O3s-824.2-742.287.4FeSO4s-928.4-820.8107.5H2g00130.7H+aq000HBrg-36.3-53.4198.7HClg-92.3-95.3186.9HCO3-aq-692.0-586.891.2HCHOg-108.6-102.5218.8H

10、COOHl-425.0-361.4129.0HFg-273.3-275.4173.8HIg26.51.7206.6HNO3l-174.1-80.7155.6H2Ol-285.8-237.170.0g-241.8-228.6188.8H2O2l-187.8-120.4109.6g-136.3-105.6232.7H2Sg-20.6-33.4205.8H2SO4l-814.0-690.0156.9HgOs-90.8-58.570.3I2s00116.1g62.419.3260.7I-aq-55.2-51.6111.3Ks0064.7K+aq-252.4-283.3102.5物 质状态fHmq/(k

11、J·mol-1)fGmq/(kJ·mol-1)Smq/(J·mol-1·K-1)KCls-436.5-408.582.6KClO3s-397.7-296.3143.1Li+aq-278.5-293.313.4Mgs0032.7Mg2+aq-466.9-454.8-138.1MgCl2s-641.3-591.889.6MgOs-601.6-569.327.0Mg(OH)2s-924.5-833.563.2MgSO4s-1284.9-1170.691.6Mn2+aq-220.8-228.1-73.6MnO2s-520.0-465.153.1MnO4-aq-5

12、41.4-447.2191.2N2g00191.6Nas0051.3Na+aq-240.1-261.959.0NaCls-411.2-384.172.1Na2CO3s-1130.7-1044.4135.0NaFs-576.6-546.351.1Na2Os-414.2-375.575.1NaOHs-425.6-379.540.0NH3g-45.9-16.4192.8NH4+aq-132.5-79.3113.4NH4NO3s-365.5-183.9151.1NOg91.387.6210.8NO2g33.251.3240.1NO3-aq-207.4-111.3146.4O2g00205.2O3g14

13、2.7163.2238.9OH-aq-230.0-157.2-10.8P4g58.924.4280.0PCl3g-287.0-267.8311.8PCl5g-374.9-305.0364.6PO43-aq-1277.4-1018.7-220.5S(正交)s0032.1SO2g-296.8-300.1248.2SO3g-395.7-371.1256.8Sis0018.8SiCl4l-687.0-619.8239.7g-657.0-617.0330.7SiH4g34.356.9204.6SiO2s-910.7-856.341.5Sn(白)s0051.2物 质状态fHmq/(kJ·mol-

14、1)fGmq/(kJ·mol-1)Smq/(J·mol-1·K-1)SnO2s-577.6-515.849.0Zns0041.6ZnOs-350.5-320.543.7附录2 常见弱电解质的标准解离常数(298.15K)附录2.1酸名 称化 学 式KaqpKaq砷酸H3AsO4Ka1q 5.50×10-32.26Ka2q 1.74×10-76.76Ka3q 5.13×10-1211.29亚砷酸H3AsO3 5.13×10-109.29硼酸H3BO3 5.81×10-109.236焦硼酸H2B4O7Ka1q 1.00

15、×10-44.00Ka2q 1.00×10-99.00碳酸H2CO3Ka1q 4.47×10-76.35Ka2q 4.68×10-1110.33铬酸H2CrO4Ka1q 1.80×10-10.74Ka2q 3.20×10-76.49氢氟酸HF 6.31×10-43.20亚硝酸HNO2 5.62×10-43.25过氧化氢H2O2 2.4×10-1211.62磷酸H3PO4Ka1q 6.92×10-32.16Ka2q 6.23×10-87.21Ka3q 4.80×10-1312.

16、32焦磷酸H4P2O7Ka1q 1.23×10-10.91Ka2q 7.94×10-32.10Ka3q 2.00×10-76.70Ka4q 4.79×10-109.32氢硫酸H2SKa1q 8.90×10-87.05Ka2q 1.26×10-1413.9亚硫酸H2SO3Ka1q 1.40×10-21.85Ka2q 6.31×10-27.20硫酸H2SO4Ka2q 1.02×10-21.99偏硅酸H2SiO3Ka1q 1.70×10-109.77Ka2q 1.58×10-1211.80甲

17、酸HCOOH 1.772×10-43.75醋酸CH3COOH 1.74×10-54.76草酸H2C2O4Ka1q 5.9×10-21.23Ka2q 6.46×10-54.19酒石酸HOOC(CHOH)2COOHKa1q 1.04×10-32.98Ka2q 4.57×10-54.34苯酚C6H5OH 1.02×10-109.99名 称化 学 式KaqpKaq抗坏血酸Ka1q 5.0×10-54.10Ka2q 1.5×10-1011.79柠檬酸HO-C(CH2COOH)2 COOHKa1q 7.24×

18、;10-43.14Ka2q 1.70×10-54.77Ka3q 4.07×10-76.39苯甲酸C6H5COOH 6.45×10-54.19邻苯二甲酸C6H4(COOH)2Ka1q 1.30×10-32.89Ka2q 3.09×10-65.51附录2.2碱名 称化 学 式KbqpKbq氨水NH3·H2O1.79×10-54.75甲胺CH3NH24.20×10-43.38乙胺C2H5NH24.30×10-43.37二甲胺(CH3)2NH5.90×10-43.23二乙胺(C2H5)2NH6.31&#

19、215;10-43.2苯胺C6H5NH23.98×10-109.40乙二胺H2NCH2CH2NH2Kb1q 8.32×10-54.08Kb2q 7.10×10-87.15乙醇胺HOCH2CH2NH23.2×10-54.50三乙醇胺(HOCH2CH2)3N5.8×10-76.24六次甲基四胺(CH2)6N41.35×10-98.87吡啶C5H5N1.80×10-98.70附录3 常见难溶电解质的溶度积(298.15K，离子强度I=0)化学式KspqpKspq化学式KspqpKspqAgBr5.35×10-1312.2

20、7CaF23.45×10-1110.46Ag2CO38.46×10-1211.07CdS8.0×10-2726.10AgCl1.77×10-109.75CoS()4.0×10-2120.40Ag2CrO41.12×10-1211.95CoS()2.0×10-2524.70AgI8.52×10-1716.07Cr(OH)36.3×10-3130.20AgOH2.0×10-87.71CuBr6.27×10-98.20Ag2S6.3×10-5049.20CuCl1.72×

21、10-76.76Al(OH)3(无定形)1.3×10-3332.89CuI1.27×10-1211.90BaCO32.58×10-98.59CuS6.3×10-3635.20BaC2O41.6×10-76.79Cu2S2.5×10-4847.60BaCrO41.17×10-109.93CuSCN1.77×10-1312.75BaSO41.08×10-109.97FeC2O4×2H2O3.2×10-76.50CaCO33.36×10-98.47Fe(OH)24.87×

22、10-1716.31CaC2O4×H2O2.32×10-98.63Fe(OH)32.79×10-3938.55化学式KspqpKspq化学式KspqpKspqFeS6.3×10-1817.20PbCO37.40×10-1413.13Hg2Cl21.43×10-1817.84PbC2O44.8×10-109.32Hg2I25.2×10-2928.72PbCrO42.8×10-1312.55HgS(红)4.0×10-5352.40PbF23.3×10-87.48HgS(黑)1.6×

23、;10-5251.80PbI29.8×10-98.01MgCO36.82×10-65.17Pb(OH)21.43×10-2019.84MgC2O4×2H2O4.83×10-65.32PbS8.0×10-2827.10MgF25.16×10-1110.29PbSO42.53×10-87.60MgNH4PO42.5×10-1312.60SrCO35.60×10-109.25Mg(OH)25.61×10-1211.25SrSO43.44×10-76.46Mn(OH)21.9

24、5;10-1312.72Sn(OH)25.45×10-2726.26MnS2.5×10-1312.60Sn(OH)41.0×10-5656.00Ni(OH)25.48×10-1615.26Zn(OH)2(无定形)3×10-1716.5NiS ()3.2×10-1918.49ZnS()1.6×10-2423.80NiS ()1.0×10-2424.00ZnS()2.5×10-2221.60附录4 常见氧化还原电对的标准电极电势Eq附录4.1在酸性溶液中电 对电 极 反 应Eq/ VLi+/ LiLi+ +

25、e Li-3.0401Cs+/CsCs+ + e Cs-3.026K+ / KK+ + e K-2.931Ba2+ / BaBa2+ + 2e Ba-2.912Ca2+ / CaCa2+ + 2e Ca-2.868Na+ / NaNa+ + e Na-2.71Mg2+/ MgMg2+ + 2e Mg-2.372H2 / H-1/2 H2 + e H-2.23Al3+ /AlAl3+ + 3e Al-1.662Mn2+ / MnMn2+ + 2e Mn-1.185Zn2+ / ZnZn2+ + 2e Zn-0.7618Cr3+ /CrCr3+ + 3e Cr-0.744Ag2S /Ag-Ag2S

26、 +2e 2Ag + S2-0.691CO2 / H2C2O42CO2 + 2H+ + 2e H2C2O4-0.481Fe2+ / FeFe2+ + 2e Fe-0.447Cr3+/ Cr2+Cr3+ + e Cr2+-0.407Cd2+/ CdCd2+ + 2e Cd-0.4030PbSO4/ Pb PbSO4 +2e Pb + SO42-0.3588Co2+/CoCo2+ + 2e Co-0.28PbCl2/ PbPbCl2 +2e Pb +2Cl-0.2675Ni2+ / NiNi2+ + 2e Ni-0.257电 对电 极 反 应Eq/ VAgI /AgAgI + e Ag + I-0

27、.15224Sn2+ / SnSn2+ + 2e Sn-0.1375Pb2+ / PbPb2+ + 2e Pb-0.1262Fe3+ / FeFe3+ +3e Fe-0.037AgCN / AgAgCN + e Ag + CN-0.017H+ / H22H+ + 2e H20.0000AgBr /Ag AgBr + e Ag + Br- 0.07133S/H2SS + 2H+ + 2e H2S (aq)0.142Sn4+/Sn2+Sn4+ + 2e Sn2+0.151Cu2+/Cu+Cu2+ + e Cu+0.153AgCl/Ag AgCl + e Ag + Cl 0.22233Hg2Cl2/

28、Hg Hg2Cl2 +2e 2Hg +2Cl-0.26808Cu2+ /CuCu2+ + 2e Cu0.3419S2O32-/S S2O32- + 6H+ + 4e 2S + 3H2O 0.5Cu+ /CuCu+ + e Cu0.521I2 / II2 + 2e 2I0.5355I3/ II3 + 2e 3I0.536MnO4/ MnO42-MnO4- + e MnO42-0.558H3AsO4/HAsO2 H3AsO4 + 2H+ + 2e HAsO2 + 2H2O 0.560Ag2SO4/Ag Ag2SO4 +2e 2Ag + SO42-0.654O2 / H2O2O2 + 2H+ + 2

29、e H2O20.695Fe3+ /Fe2+ Fe3+ + e Fe2+ 0.771Hg22+/ HgHg22+ + 2e 2Hg0.7973Ag+ /AgAg+ + e Ag0.7996NO3- /N2O42NO3- + 4H+ + 2e N2O4 + 2H2O0.803Hg2+ / HgHg2+ + 2e Hg0.851Cu2+ /CuICu2+ + I- + e CuI0.86Hg2+/Hg22+2Hg2+ + 2e Hg22+0.920NO3- / HNO2 NO3- + 3H+ + 2e HNO2 + H2O 0.934NO3- / NO NO3- + 4H+ + 3e NO + 2H

30、2O0.957HNO2 / NO HNO2 + H+ + e NO + H2O0.983AuCl4/Au AuCl4 + 3e Au + 4Cl1.002Br2 / Br-Br2(l) + 2e 2Br-1.066Cu2+ / Cu(CN)2Cu2+ + 2CN- + e Cu(CN)21.103IO3- / HIO IO3- + 5H+ + 4e HIO + 2H2O 1.14IO3- / I2 2IO3- + 12H+ + 10e I2 + 6H2O1.195MnO2/ Mn2+ MnO2 + 4H+ +2e Mn2+ + 2H2O1.224O2 / H2OO2 + 4H+ + 4e 2H

31、2O1.229Cr2O72- /Cr3+ Cr2O72- + 14H+ + 6e 2Cr3+ + 7H2O1.232Cl2 /Cl- Cl2(g) + 2e 2Cl- 1.35827ClO4-/Cl22ClO4- + 16H+ + 14e Cl2 + 8H2O1.39ClO3-/Cl- ClO3- + 6H+ + 6e Cl- + 3H2O1.451电 对电 极 反 应Eq/ VPbO2 /Pb2+ PbO2 + 4H+ +2e Pb2+ + 2H2O1.455ClO3-/Cl2 ClO3- + 6H+ + 5e 1/2 Cl2 + 3H2O1.47BrO3- /Br2 2BrO3- + 12

32、H+ + 10e Br2 + 6H2O1.482HClO /Cl- HClO + H+ + 2e Cl- + H2O1.482Au3+ /AuAu3+ + 3e Au1.498MnO4-/Mn2+ MnO4- + 8H+ + 5e Mn2+ + 4H2O1.507Mn3+ / Mn2+Mn3+ + e Mn2+1.5415HBrO / Br2 2HBrO + 2H+ + 2e Br2 + 2H2O1.596H5IO6 / IO3H5IO6 + H+ + 2e IO3 + 3H2O1.601HClO /Cl2 2HClO + 2H+ + 2e Cl2 + 2H2O1.611HClO2 /HClO

33、HClO2 + 2H+ + 2e HClO + H2O1.645MnO4/ MnO2 MnO4 + 4H+ + 3e MnO2 + 2H2O1.679PbO2 / PbSO4 PbO2 + SO42- + 4H+ +2e PbSO4 + 2H2O1.6913H2O2 / H2OH2O2 + 2H+ + 2e 2H2O1.776Co3+ / Co2+Co3+ + e Co2+1.92S2O82- / SO42-S2O82 + 2e 2SO42-2.010O3 / O2 O3 + 2H+ + 2e O2 + H2O2.076F2 / F-F2 + 2e 2F-2.866F2 / HFF2(g) +

34、 2H+ + 2e 2HF3.503附录4.2在碱性溶液中电 对电 极 反 应Eq/ VMn(OH)2 / MnMn(OH)2 + 2e Mn + 2OH-1.56Zn(CN)42- / ZnZn(CN)42- + 2e Zn + 4CN-1.34ZnO22- / ZnZnO22- + 2H2O + 2e Zn + 4OH-1.215Sn(OH)62- / HSnO2-Sn(OH)62- + 2e HSnO2- + 3OH- + H2O -0.93SO42- / SO32-SO42- + H2O + 2e SO32- + 2OH-0.93HSnO2- / SnHSnO2- + H2O + 2e

35、 Sn + 3OH-0.909H2O/ H22H2O + 2e H2 + 2OH-0.8277Ni(OH)2 / NiNi(OH)2 +2e Ni + 2OH-0.72AsO43- / AsO2-AsO43- + 2H2O + 2e AsO2- + 4OH-0.71SO32- / SSO32- + 3H2O + 4e S + 6OH-0.59SO32- / S2O32-2SO32- + 3H2O + 4e S2O32- + 6OH-0.571S /S2-S + 2e S2-0.47627Ag(CN)2- /AgAg(CN)2- + e Ag + 2CN-0.31CrO42-/ CrO2-CrO

36、42- + 4H2O + 3e Cr(OH)4- + 4OH-0.13O2 / HO2-O2 + H2O + 2e HO2- + OH-0.076NO3- / NO2-NO3- + H2O + 2e NO2- + 2OH-0.01S4O62- / S2O32-S4O62- + 2e 2S2O32-0.08Co(NH3)63+/ Co(NH3)62+Co(NH3)63+ + e Co(NH3)62+0.108MnO2/ Mn2+ Mn(OH)3 +e Mn(OH)2 + OH-0.15Cr2O72- /Cr3+ Co(OH)3 +e Co(OH)2 + OH-0.17电 对电 极 反 应Eq/

37、VAg2O/AgAg2O + H2O + 2e 2Ag + 2OH- 0.342O2 / OH-O2 + 2H2O + 4e 4OH- 0.401MnO4-/ MnO2 MnO4- + 2H2O + 3e MnO2 + 4OH-0.595BrO3- / Br BrO3- + 3H2O + 6e Br + 6OH-0.61BrO- / Br BrO- + H2O + 2e Br + 2OH-0.761ClO-/ Cl-ClO- + H2O + 2e Cl- + 2OH-0.81H2O2 / OH-H2O2 + 2e 2OH-0.88O3 / OH- O3 + H2O + 2e O2 + 2OH-

38、1.24附录5 一些氧化还原电对的条件电极电势Eq电极反应Eq / V介质Ag() + e Ag+1.9274mol·L-1HNO3Ce() + e Ce()1.701mol·L-1HClO41.611mol·L-1HNO31.440.5mol·L-1H2SO41.281mol·L-1HClCo(en)33+ + e Co(en)32+-0.200.1mol·L-1KNO3 + 0.1mol·L-1 enCr2O72- + 14H+ + 6e 2Cr3+ + 7H2O1.0001mol·L-1HCl1.0301mo

39、l·L-1HClO41.0803mol·L-1HCl1.0502mol·L-1HCl1.1504mol·L-1H2SO4CrO42- + 2H2O + 3e CrO2- + 4OH-0.1201mol·L-1NaOHFe() + e Fe()0.7501mol·L-1HClO40.6700.5mol·L-1H2SO40.7001mol·L-1HCl0.4602mol·L-1H3PO4H3AsO4 + 2H+ + 2e H3AsO3 + H2O 0.5571mol·L-1HClH2SO3 + 4H

40、+ + 4e S + 3H2O0.5571mol·L-1HClO4Fe(EDTA)- + e Fe(EDTA)2-0.1200.1mol·L-1EDTA(pH=46)Fe(CN)63- + e Fe(CN)64-0.4800.01mol·L-1HCl0.5600.1mol·L-1HCl0.7201mol·L-1HClO4I2(水)+ 2e 2I-0.62761mol·L-1H+MnO4- + 8H+ + 5e Mn2+ + 4H2O1.4501mol·L-1HClO41.278mol·L-1H3PO4SnCl62-

41、 + 2e SnCl42- +2Cl-0.1401mol·L-1HClSn2+ + 2e Sn-0.1601mol·L-1HClO4Sb() + 2e Sb()0.7503.5mol·L-1HClSb(OH)6- + 2e SbO2- +2OH- + 2H2O-0.4283mol·L-1NaOHSbO2- + 2H2O + 3e Sb + 4OH- -0.67510mol·L-1KOHTi() + e Ti()-0.0100.2mol·L-1H2SO4电极反应Eq / V介质0.1202mol·L-1H2SO4-0.0401

42、mol·L-1HClPb() + 2e Pb-0.3201mol·L-1NaAc-0.1401mol·L-1HClO4附录6 常见配离子的稳定常数配位体金属离子nlgnNH3Ag+1, 23.24, 7.05Cu2+1, 44.31, 7.98, 11.02, 13.32Ni2+1, 62.80, 5.04, 6.77, 7.96, 8.71, 8.74Zn2+1, 42.37, 4.81, 7.31, 9.46F-Al3+1, 66.10, 11.15, 15.00, 17.75, 19.37, 19.84Fe3+1, 2, 35.28, 9.30, 12.06

43、Cl-Hg2+1, 46.74, 13.22, 14.07, 15.07CN-Ag+2, 3, 421.1, 21.7, 20.6Fe2+635Fe3+642Ni2+431.3Zn2+416.7S2O32-Ag+1, 28.82, 13.46Hg2+2, 3, 429.44, 31.90, 33.24OH-Al3+1, 49.27, 33.03Bi3+1, 2, 412.7, 15.8, 35.2Cd2+1, 44.17, 8.33, 9.02, 8.62Cu2+1, 47.0, 13.68, 17.00, 18.5Fe2+1, 45.56, 9.77, 9.67, 8.58Fe3+1, 2,

44、 311.87, 21.17, 29.67Hg2+1, 2, 310.6, 21.8, 20.9Mg2+12.58Ni2+1, 2, 34.97, 8.55, 11.33Pb2+1, 2, 3, 67.82, 10.85, 14.58, 61.0Sn2+1, 2, 310.60, 20.93, 25.38Zn2+1, 44.40, 11.30, 14.14, 17.66EDTAAg+17.32Al3+116.11Ba2+17.78Bi3+122.8Ca2+111.0Cd2+116.4Co2+116.31Co3+136.00配位体金属离子nlgnEDTACr3+123Cu2+118.70Fe2+

45、114.33Fe3+124.23Hg2+121.80Mg2+18.64Mn2+113.8Ni2+118.56Pb2+118.3Sn2+122.1Zn2+116.4注：表中数据为2025、I=0的条件下获得。附录7 相对分子质量AgBr187.772CaF278.075CrCl3158.354AgCl143.321Ca(NO3)2164.087Cr(NO3)3238.011AgCN133.886Ca(OH)274.093Cr2O3151.990AgSCN165.952Ca3(PO4)2310.177CuCl98.999Ag2CrO4331.730CaSO4136.142CuCl2134.451A

46、gI234.772CdCO3172.420CuSCN121.630AgNO3169.873CdCl2183.316CuI190.450AlCl3133.340CdS144.477Cu(NO3)2187.555Al2O3101.961Ce(SO4)2332.24CuO79.545Al(OH)378.004CH3COOH60.05Cu2O143.091Al2(SO4)3342.154CH3OH32.04CuS95.612As2O3197.841CH3COCH358.08CuSO4159.610As2O5229.840C6H5COOH122.12FeCl2126.750As2S3246.041C6H

47、5COONa144.11FeCl3162.203BaCO3197.336C6H4COOHCOOK204.22Fe(NO3)3241.862BaC2O4225.347CH3COONH477.08FeO71.844BaCl2208.232CH3COONa82.03Fe2O3159.688BaCrO4253.321C6H5OH94.11Fe3O4231.533BaO153.326(C9H7N)3H3PO4×12MoO32212.74Fe(OH)3106.867Ba(OH)2171.342(磷钼酸喹啉)FeS87.911BaSO4233.391COOHCH2COOH104.06Fe2S320

48、7.87BiCl3315.338COOHCH2COONa126.04FeSO4151.909BiOCl260.432CCl4153.82Fe2(SO4)3399.881CO244.010CoCl2129.838H3AsO3125.944CaO56.077Co(NO3)2182.942H3AsO4141.944CaCO3100.087CoS91.00H3BO361.833CaC2O4128.098CoSO4154.997HBr80.912CaCl2110.983CO(NH2)260.06HCN27.026HCOOH46.03KHC2O4×H2C2O4×2H2O254.20(NH4)2S68.143H2CO362.0251KHC4H4O6188.178(NH4)2S